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  1. Free, publicly-accessible full text available September 1, 2024
  2. From 2017-2021, Mississippi State University’s Department of Chemistry has hosted a 10-week summer Research Experience for Undergraduates (REU) program, focused on research related to food, energy, and water security topics. The goals of this program were to train students by providing an intensive research experience, recruit minority and underrepresented students, and provide advising for future career goals. The program hosted a growing cohort of undergraduate students each summer, 113 in total, recruited from a pool of underrepresented students and those with limited research opportunities. The pre- and post-program survey results covering three summers showed consistent self-reported growth among the student cohort in the program’s focused skill sets. This manuscript presents three years of the program’s success, from initial planning stages and recruitment to final results including a description of the value of each program component. 
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  3. Slag and Al/Mg oxide modified Douglas fir biochar (AMOB) were compared for their phosphate adsorbing abilities for use individually or in combination for simulated agriculture run-off remediation in wetlands. Aqueous batch and column sorption experiments were performed for both low-cost materials. AMOB was prepared in bulk using a novel green method. Material analyses included XRD, elemental analysis, SEM, EDX, and BET. Biochar and slag have different phosphate removal mechanisms. In short residence times (≤2 h), adsorption phenomena dominate for both adsorbents. Surface area likely plays a role in adsorption performance; slag was measured to be 4.1 m2/g while biochar’s surface area was 364.1 m2/g. In longer residence times (>2 h), the slow leaching of metals (Ca, Al, and Mg) from slag continue to remove phosphate through the precipitation of metal phosphates. In 24 h, slag removed more free phosphate from the solution than AMOB. Preliminary fixed bed column adsorption of slag or AMOB alone and in tandem was performed adopting a scaled-up model that can be used to remediate agricultural runoff with high phosphate content. Additionally, a desorption study was performed to analyze the efficiency of material regeneration. While AMOB does not release any adsorbed phosphates, slag slowly releases 5.7% adsorbed phosphate over seven days. 
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